Proyectos de Investigación

2021

313. "Rationalizing the influence of α-cationic phospholes on pi-catalysis".  I. Cortés, J. J. Cabrera-Trujillo, I. Fernández, Dalton Trans. 2021, 50, 18036. pdf 

312. "Nature of C-I···π halogen bonding and its role in organocatalysis".  S- Portela, I. Fernández, Eur. J. Org. Chem. 2021, 45, 6102. pdf

311. "Stannylenes based on pyrrole-phosphane and dipyrromethanediphosphane scaffolds: Syntheses and behavior as PSnP pincer Ligands".  J. A. Cabeza, I. Fernández, P. García-Álvarez, R. García-Soriano, C. J. Laglera-Gándara, R. Torala, Dalton Trans. 2021, 50, 16122. pdf 

310. HOT PAPER"Gold-Catalyzed Reaction of Propargyl Esters and Alkynylsilanes: Synthesis of Vinylallene Derivatives through a Twofold 1,2-Rearrangement".  O. Bernardo, S. González-Pelayo, I. Fernández, L. A. López, Angew. Chem. Int. Ed. 2021, 22, 25258. pdf 

309. HOT PAPER"Reduction of Nitrogen Oxides by Hydrogen with Rh(I)-Pt(II) Olefin Complexes as Catalysts". P. Jurt, A. S. Abels, J. J. Gamboa-Carballo, I. Fernández, G. Le Corre, M. Aebli, M. G. Baker, F. Eiler, F. Müller, M. Wörle, R. Verel, S. Gauthier, M. Trincado, T. L. Gianetti, H. Grützmacher, Angew. Chem. Int .Ed. 2021, 22, 25372. pdf 

308. "Regioselective Monoborylation of Spirocyclobutenes". L. Novoa, L. Trulli, I. Fernández, A. Parra, M. Tortosa, Org. Lett2021, 23, 7434. pdf 

307. "A Dicoordinate Gold(I)–Ethylene Complex". M. Navarro, J. Miranda-Pizarro, J. J. Moreno, C. Navarro-Gilabert, I. Fernández, J. Campos, Chem. Commun2021, 57, 9280. pdf HIGHLIGHTED in Chemistry Views, see here

306. "Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes". D. A. Cruz, V. Sinka, P. de Armas, H. S. Steingruber, I. Fernández, V. S. Martín, P. O. Miranda, J. I. Padrón, Org. Lett2021, 23, 6105. pdf 

305. "Helically Arranged Chiral Molecular Nanographenes". P. Izquierdo-García, J. M. Fernández-García, I. Fernández, J. Perles, N. Martín, J. Am. Chem. Soc. 2021, 143, 11864. pdf 

304. "Scope and mechanistic investigations of Pd-catalyzed coupling/cyclizations and cycloisomerizations of allenyl malonates". L. E. Vine, R. D. Reeves, E. M. Landwehr, I. Fernández, J. M. Schomaker, ACS Catal. 2021, 11, 9485. pdf 

303. HOT PAPER"Factors Controlling the Aluminium(I)-meta-selective C-H Activation in Arenes". J. J. Cabrera-Trujillo, I. Fernández, Chem. Eur. J. 2021, 27, 12422. pdf 

302. BOOK CHAPTER "Quantifying Aromaticity According to the Energetic criterion".  M. Alonso, I. Fernández, in Aromaticity: Modern Computational Methods and Applications, ch. 6, Ed. I. Fernández, Elsevier, 2021. pdf 

301. “Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- and Alkynylsilanes under Gold-Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes”.  O. Bernardo, K. Yamamoto, I. Fernández, L. A. López, Org. Lett. 2021, 1, 623. pdf 

300. “Metal–CO Bonding in Mononuclear Transition Metal Carbonyl Complexes”.  G. Frenking, I. Fernández, N. Holzmann, S. Pan, I. Krossing, M. Zhou, JACS Au 2021, 1, 623. pdf 

299. “Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn—Zn Bond Cleavage and Cooperative Reactivity”.  N. Hidalgo, C. Romero-Pérez, C. Maya, I. Fernández, J. Campos, Organometallics 2021, 40, 1113. pdf 

298. “Origin of the Ir-Si Bond Shortening in Ir-NSiN complexes”.  P. García-Orduña, I. Fernández, L. A. Oro, F. J. Fernández-Alvarez, Dalton Trans. 2021, 50, 5951. pdf 

297.  HOT PAPER “Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table ”.  P. Vermeeren, M. Dalla Tiezza, M. van Dongen, I. Fernández, F. M. Bickelhaupt, T. A. Hamlin, Chem. Eur. J. 2021, 27, 10610. pdf 

296. “Catalysis by Bidentate Iodine(III)-based Halogen donors: Surpassing the activity of strong Lewis acids”.  S. Portela, J. J. Cabrera-Trujillo, I. Fernández, J. Org. Chem. 2021, 27, 5180. pdf 

295. “Nature of the Hydrogen Bond Enhanced Halogen Bond”.  S. Portela I. Fernández, Molecules 2021, 26, 1885. pdf (INVITED FOR Special Issue Chemical Bonding: A Commemorative Special Issue Honoring Professor Linus Pauling)

294. “The Pauli Repulsion-Lowering Concept in Catalysis”.  T. A. Hamlin, F. M. Bickelhaupt, I. Fernández, Acc. Chem. Res. 2021, 54, 1972. pdf  COVER

293. “Assembly of a Dihydrideborate and two Aryl Nitriles to Form a C,N,N’-Pincer Ligand Coordinated to Osmium”.  J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate, Organometallics 2021, 40, 635. pdf 

292. “Reactions of Late First-Row Transition Metal (Fe–Zn) Dichlorides with a PGeP Pincer Germylene”.  A. Arauzo, J. A. Cabeza, I. Fernández, P. García-Álvarez, I. García-Rubio, C. J. Laglera-Gándara, Chem. Eur. J. 2021, 27, 4985. pdf 

291. “Iron-promoted dealkylative carbene aminocyclization of δ-arylamino-α-diazoesters”.  D. Solé, A. Amenta, C. Campos, I. Fernández, Dalton Trans. 2021, 50, 2167. pdf 

290. “Highly Enantioselective Cobalt-Catalyzed (3 + 2) Cycloadditions of Alkynylidenecyclopropanes”.  E. Da Concepción, I. Fernández, J. L. Mascareñas, F. López, Angew. Chem. Int. Ed. 2021, 60, 8182. pdf 

289. “Understanding the C–F Bond Activation Mediated by Frustrated Lewis Pairs: Crucial Role of Noncovalent Interactions".  J. J. Cabrera-Trujillo, I. Fernández, Chem. Eur. J. 2021, 27, 3823. pdf 

288.  HOT PAPER “Bifunctional Hydrogen Bond Donor-Catalyzed Diels-Alder Reactions: Origin of Stereoselectivity and Rate Enhancement ”.  P. Vermeeren, T. A. Hamlin, F. M. Bickelhaupt, I. Fernández, Chem. Eur. J. 2021, 27, 5180. pdf COVER

287. “Catalytic Conversion of Alkynes to a-Vinyl Sulfides Mediated by Carbene-linker-Carbene (CXC) Rhodium and Iridium Complexes”.  L. C. Tolley, I. Fernández, D. I. Bezuidenhout, G. Guisado-Barrios, Catal. Sci. Technol. 2021, 11, 516. pdf