403. "Mechanism and Origin of Regioselectivity in the Phosphine-Catalyzed Heine Reaction". S. Gallardo-Fuentes, L. Lodeiro, I. Fernández, J. Org. Chem. 2025, 90, 6538 pdf Invited for the special issue: “Physical Organic Chemistry: Never Out of Style”

402. "Stabilities and Limitations in the Reactivity of Phosphorus Ylide-Based Aluminum- and Gallium-Carbon Ambiphiles − A Combined Experimental and Computational Approach". F. Krämer, P. Weisenburger, I. Fernández, F. Breher, Eur. J. Inorg. Chem. 2025, in press. pdf

401. "Reactions of 1,4-diborinine derivatives with CO₂". M. Ferrer, I. Alkorta, J. Elguero, I. Fernández, ChemPhysChem 2025, in press. pdf

400. "σ-BH activation of NHC→BH₃ fragments at dinuclear Cu complexes". A. Camy, D. Martins-Bessa, L. Vendier, I. Fernández, S. Bontemps, Dalton Trans. 2025, 54, 7333. pdf

399. "Influence of the Nature of Group 15 Element on the [Au^I]-CE/azide 1,3-Dipolar Cycloaddition Reaction". D. González-Pinardo, I. Fernández, Inorg. Chem. 2025, 64, 5628. pdf

398. "Enantioselective photocatalytic synthesis of bicyclo[2.1.1]hexanes as orthodisubstituted benzene bioisosteres with improved biological activity". P. Garrido-García, I. Quirós, P. Milán-Rois, S. Ortega-Gutiérrez, M. Martín-Fontecha, L. A. Campos, Á. Somoza, I. Fernández, T. Rigotti, M. Tortosa, Nat. Chem. 2025, 17, 734. pdf

397. "Stepwise Alkyne Insertion in Au(I) Acetylides: Influence of the Nuclearity". J. Cayuela-Castillo, F. J. Fernández-de-Córdova, M. S. See, I. Fernández, P. Ríos, Chem. Sci. 2025, 16, 4684. pdf Selected as 2025 Chemical Science HOT Article

396. "An Open-Shell Ir^II/Ir^IV Redox Couple Outperforms the Conventional Ir^I/Ir^III Pair for the Catalytic Isomerization of Olefins". A. Pita-Milleiro, N. Hidalgo, J. J. Moreno, I. Fernández, J. Campos, Nat. Chem. 2025, 17, 607. pdf

395. "Extended Tetrathiafulvalene Multi-Redox Systems Incorporating 4,5-Dihydroazuleno[2,1,8-ija]azulene Cores". V. B. R. Pedersen, M. Zalibera, F. Lirette, J. Ouellette, A. Lanza, I. Fernández, P. Rapta, J.-F. Morin, M. B. Nielsen, Angew. Chem. Int. Ed. 2025, 64, e202422275. pdf

394. "Disclosing the intra-catalyst non-covalent interactions in tetrahydropyran-based dipeptidic catalysts". I. García-Monzón, J. Borges-González, E. Q. Morales, I. Fernández, T. Martín, Adv. Synth. Catal. 2025, 367, e202401443. pdf

393. "Insight into the Key Factors that Influence the Reaction Pathways in the Silyl-Prins Cyclization of gem-Vinylsilyl Alcohols". P. González-Andrés, C. Díez-Poza, L. F. Peña, D. Gónzalez-Pinardo, I. Fernández, A. Barbero, Adv. Synth. Catal. 2025, 367, e202401437. pdf

392. "Cross-Dehydrogenative Coupling of Secondary Amines with Silanes Catalyzed by Agostic Iridium-NSi Species". M. Padilla, M. Batuecas, P. García-Orduña, I. Fernández, F. J. Fernández-Álvarez, Inorg. Chem. 2025, 64, 255. pdf

391. "Visible Light-Mediated [4+2] Annulation of Silylimines with Olefins to 1-Aminotetralins Enabled by Diradical Hydrogen Atom Transfer of C−H Bonds". Q. Liu, Y. Huang, X. Zhou, I. Fernández, Y. Xiong, Angew. Chem. Int. Ed. 2025, 64, e202421464. pdf THIS ARTICLE HAS BEEN HIGHLIGHTED (see: Synfacts 2025, 21, 308)

390. "Cooperative hydrogenation catalysis at a constrained gallylene-nickel(0) interface". T. L. Kalkuhl, I. Fernández, T. J. Hadlington, Chem 2025, 11, 102349. pdf

389. "Understanding the Reactivity and Selectivity of Oxazaborolidium ion-Catalyzed Diels-Alder Reactions Involving Cyclobutenones as Dienophiles". S. Portela, I. Fernández, ChemPlusChem 2025, 90, e202400684. pdf invited for the special collection titled From Computer to Bench and Back: In Silico Elucidation of Organocatalytic Reaction Mechanisms

388. "π-Conjugation as a Direct Estimate of Lewis Acidity". D. González-Pinardo, I. Fernández, Chem. Asian J. 2025, 20, e202401212. pdf SELECTED FOR COVER PAGE

387. "Synthesis of Contorted Polycyclic Aromatic Compounds via Alkyne Benzannulation on Dibenzochrysene Derivatives". A. Darvish, F. Lirette, I. Fernández, J.-F. Morin, Chem. Eur. J. 2025, 31, e202403456. pdf