2025
420. "Snapshots of Cooperative Trimetallic Alkene Hydrogenation". T. L. Kalkuhl, I. Fernández, T. J. Hadlington, J. Am. Chem. Soc. 2025, 147, 46373. pdf
419. "Cyclopropylmethyl Boronic Esters as General Reagents in Transition-Metal Catalyzed Homoallylation Reactions". B. Lozano, J. Teresa, I. Fernández, M. Tortosa, J. Am. Chem. Soc. 2025, 147, 41221. pdf
418. "Harnessing exo-Enol Ether Glycosides: Direct Synthesis of Tricyclic Epoxybenzoxocine Cores via a Programmed Cationic Cascade". M. Pascaretti, R. Fischbach, Y. Rieder, M. Da Silveira, P. Lafargue, C. Triballeau, D. González-Pinardo, I. Fernández, D. Hazelard, P. Compain, Org. Lett. 2025, 27, 12600.pdf
417. "Tuneable zinc scorpionates for CO2 fixation into sustainable materials: access to polycarbonates and tailored hybrid poly(L-lactide)s-b-polycarbonates". M. Navarro, D. González, A. Lara-Sánchez, I. Fernández, C. Moya-López, L. F. Sánchez-Barba, A. Garcés, Eur. Polym. J. 2025, 241, 114361.pdf
416. "Exploring the Role of Halogen Bond Donors in the Thiourea‐Catalyzed Friedel–Crafts Alkylation Reaction". S. Ardevines, D. González‐Pinardo, I. Fernández, E. Marqués‐López, R. P. Herrera, ChemCatChem 2025, 17, e01060.pdf
415. "Unveiling the Mechanism and Origins of Selectivity in Phosphine-Catalyzed Higher-Order Cycloadditions of Allenes with Tropone". S. Gallardo-Fuentes, A. F. Flor-López, P. Jaque, I. Fernández, J. Org. Chem. 2025, 90, 13703.pdf
414. "Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes". F. Krämer, M. H. Crabbe, I. Fernández, R. E. Mulvey, Angew. Chem. Int. Ed. 2025, 64, e202516376.pdf Selected as VIP article
413. "From Delocalization to Disruption: The Role of Aromaticity in N-Heterocyclic Carbenes’ Reactions with Diazoalkane and Diazoester". H. Sharma, I. Fernández, K. Vanka, J. Org. Chem. 2025, 90, 12409.pdf
412. "Aromaticity and Antiaromaticity in the Cyclic 6π and 4π Molecules of Carbon and Silicon E6H6 and E4H4 (E = C, Si)".L. Zhao, Q. Ma, I. Fernández, G. Frenking, Phys. Chem. Chem. Phys. 2025, 27, 18555.pdf
411. "Transition State Aromaticity and its Relationship with Reactivity in Pericyclic Reactions". I. Fernández, Beilstein J. Org. Chem. 2025, 21, 1613.pdf
410. "Crown Ether Supported Alkali Metal Phosphides: Synthesis,Structures and Bonding". F. Krämer, M. H. Crabbe, A. R. Kennedy, C. E. Weetman, I. Fernández, Chem. Eur. J. 2025, 31, e02127. pdf Selected as VIP article
409. "Stepwise Acetylene Insertion and Ammonia Activation at a Digallene and Diindene". A. García-Romero, I. Fernández, J. M. Goicoechea, Angew. Chem. Int. Ed. 2025, 64, e202509661. pdf
408. "Two-carbon ring expansion of bicyclic aziridines to oxazocines via aryne insertion into a σ C–N bond". D. S. Rampon, T. Anh Trinh, Y. Pan, S. Thein, J. W. Kailing, I. A. Guzei, I. Fernández, J. M. Schomaker, Chem. Sci. 2025, 16, 20368. pdf THIS ARTICLE HAS BEEN HIGHLIGHTED (see: Synfacts 2026, 22, 14)
407. "CO₂-to-Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst". E. Álvarez-Ruiz, M. Navarro, I. Sancho, I. Fernández, C. Santamaría, A. Hernán-Gómez, Adv. Synth. Catal. 2025,367, e70057. pdf
406. "Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4-diides: Interplay between Diradical Character and Aromaticity". D. González-Pinardo, R. S. Ghadwal, I. Fernández, Chem. Eur. J. 2025, 31, e202501933. pdf Selected for COVER PAGE
405. "Reduction-Induced C–C Cleavage and Site-Specific Hydrogenation of a Highly Strained Bilayer Spironanographene". J. Lión-Villar, H. S. Torchon, Y. Zhu, Z. Wei, J. M. Fernández-García, I. Fernández, M. A. Petrukhina, N. Martín, Angew. Chem. Int. Ed. 2025, 64, e202510209. pdf
404. "Diastereoselective Scholl reaction: Point-to-helical chirality transfer in molecular nanographenes". S. Marcos López, M. Buendia, I. Fernández, S. Filippone, N. Martín, Chem. Sci. 2025, 16, 12867. pdf
403. "Mechanism and Origin of Regioselectivity in the Phosphine-Catalyzed Heine Reaction". S. Gallardo-Fuentes, L. Lodeiro, I. Fernández, J. Org. Chem. 2025, 90, 6538 pdf Invited for the special issue: “Physical Organic Chemistry: Never Out of Style”
402. "Stabilities and Limitations in the Reactivity of Phosphorus Ylide-Based Aluminum- and Gallium-Carbon Ambiphiles − A Combined Experimental and Computational Approach". F. Krämer, P. Weisenburger, I. Fernández, F. Breher, Eur. J. Inorg. Chem. 2025, 28, e202500165. pdf Selected for COVER PAGE
401. "Reactions of 1,4-diborinine derivatives with CO2". M. Ferrer, I. Alkorta, J. Elguero, I. Fernández, ChemPhysChem 2025, 26, e202401049. pdf
400. "σ-BH activation of NHC→BH3 fragments at dinuclear Cu complexes". A. Camy, D. Martins-Bessa, L. Vendier, I. Fernández, S. Bontemps, Dalton Trans. 2025, 54, 7333. pdf
399. "Influence of the Nature of Group 15 Element on the [AuI]-CE/azide 1,3-Dipolar Cycloaddition Reaction". D. González-Pinardo, I. Fernández, Inorg. Chem. 2025, 64, 5628. pdf
398. "Enantioselective photocatalytic synthesis of bicyclo[2.1.1]hexanes as orthodisubstituted benzene bioisosteres with improved biological activity". P. Garrido-García, I. Quirós, P. Milán-Rois, S. Ortega-Gutiérrez, M. Martín-Fontecha, L. A. Campos, Á. Somoza, I. Fernández, T. Rigotti, M. Tortosa, Nat. Chem. 2025, 17, 734. pdf HIGHLIGHTED in Synfacts 2025, 21, 631
397. "Stepwise Alkyne Insertion in Au(I) Acetylides: Influence of the Nuclearity". J. Cayuela-Castillo, F. J. Fernández-de-Córdova, M. S. See, I. Fernández, P. Ríos, Chem. Sci. 2025, 16, 4684. pdf Selected as 2025 Chemical Science HOT Article
396. "An Open-Shell IrII/IrIV Redox Couple Outperforms the Conventional IrI/IrIII Pair for the Catalytic Isomerization of Olefins". A. Pita-Milleiro, N. Hidalgo, J. J. Moreno, I. Fernández, J. Campos, Nat. Chem. 2025, 17, 607. pdf
395. "Extended Tetrathiafulvalene Multi-Redox Systems Incorporating 4,5-Dihydroazuleno[2,1,8-ija]azulene Cores". V. B. R. Pedersen, M. Zalibera, F. Lirette, J. Ouellette, A. Lanza, I. Fernández, P. Rapta, J.-F. Morin, M. B. Nielsen, Angew. Chem. Int. Ed. 2025, 64, e202422275. pdf
394. "Disclosing the intra-catalyst non-covalent interactions in tetrahydropyran-based dipeptidic catalysts". I. García-Monzón, J. Borges-González, E. Q. Morales, I. Fernández, T. Martín, Adv. Synth. Catal. 2025, 367, e202401443. pdf
393. "Insight into the Key Factors that Influence the Reaction Pathways in the Silyl-Prins Cyclization of gem-Vinylsilyl Alcohols". P. González-Andrés, C. Díez-Poza, L. F. Peña, D. Gónzalez-Pinardo, I. Fernández, A. Barbero, Adv. Synth. Catal. 2025, 367, e202401437. pdf
392. "Cross-Dehydrogenative Coupling of Secondary Amines with Silanes Catalyzed by Agostic Iridium-NSi Species". M. Padilla, M. Batuecas, P. García-Orduña, I. Fernández, F. J. Fernández-Álvarez, Inorg. Chem. 2025, 64, 255. pdf
391. "Visible Light-Mediated [4+2] Annulation of Silylimines with Olefins to 1-Aminotetralins Enabled by Diradical Hydrogen Atom Transfer of C−H Bonds". Q. Liu, Y. Huang, X. Zhou, I. Fernández, Y. Xiong, Angew. Chem. Int. Ed. 2025, 64, e202421464. pdf THIS ARTICLE HAS BEEN HIGHLIGHTED (see: Synfacts 2025, 21, 308)
390. "Cooperative hydrogenation catalysis at a constrained gallylene-nickel(0) interface". T. L. Kalkuhl, I. Fernández, T. J. Hadlington, Chem 2025, 11, 102349. pdf
389. "Understanding the Reactivity and Selectivity of Oxazaborolidium ion-Catalyzed Diels-Alder Reactions Involving Cyclobutenones as Dienophiles". S. Portela, I. Fernández, ChemPlusChem 2025, 90, e202400684. pdf invited for the special collection titled From Computer to Bench and Back: In Silico Elucidation of Organocatalytic Reaction Mechanisms
388. "π-Conjugation as a Direct Estimate of Lewis Acidity". D. González-Pinardo, I. Fernández, Chem. Asian J. 2025, 20, e202401212. pdf SELECTED FOR COVER PAGE
387. "Synthesis of Contorted Polycyclic Aromatic Compounds via Alkyne Benzannulation on Dibenzochrysene Derivatives". A. Darvish, F. Lirette, I. Fernández, J.-F. Morin, Chem. Eur. J. 2025, 31, e202403456. pdf