2025
407. "Stepwise Acetylene Insertion and Ammonia Activation at a Digallene and Diindene". A. García-Romero, I. Fernández, J. M. Goicoechea, Angew. Chem. Int. Ed. 2025, in press. pdf
406. "Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4-diides: Interplay between Diradical Character and Aromaticity". D. González-Pinardo, R. S. Ghadwal, I. Fernández, Chem. Eur. J. 2025, in press.pdf
405. "Reduction-Induced C–C Cleavage and Site-Specific Hydrogenation of a Highly Strained Bilayer Spironanographene". J. Lión-Villar, H. S. Torchon, Y. Zhu, Z. Wei, J. M. Fernández-García, I. Fernández, M. A. Petrukhina, N. Martín, Angew. Chem. Int. Ed. 2025, in press. pdf
404. "Diastereoselective Scholl reaction: Point-to-helical chirality transfer in molecular nanographenes". S. Marcos López, M. Buendia, I. Fernández, S. Filippone, N. Martín, Chem. Sci. 2025, 16, 12867. pdf
403. "Mechanism and Origin of Regioselectivity in the Phosphine-Catalyzed Heine Reaction". S. Gallardo-Fuentes, L. Lodeiro, I. Fernández, J. Org. Chem. 2025, 90, 6538 pdf Invited for the special issue: “Physical Organic Chemistry: Never Out of Style”
402. "Stabilities and Limitations in the Reactivity of Phosphorus Ylide-Based Aluminum- and Gallium-Carbon Ambiphiles − A Combined Experimental and Computational Approach". F. Krämer, P. Weisenburger, I. Fernández, F. Breher, Eur. J. Inorg. Chem. 2025, 28, e202500165. pdf Selected for COVER PAGE
401. "Reactions of 1,4-diborinine derivatives with CO2". M. Ferrer, I. Alkorta, J. Elguero, I. Fernández, ChemPhysChem 2025, 26, e202401049. pdf
400. "σ-BH activation of NHC→BH3 fragments at dinuclear Cu complexes". A. Camy, D. Martins-Bessa, L. Vendier, I. Fernández, S. Bontemps, Dalton Trans. 2025, 54, 7333. pdf
399. "Influence of the Nature of Group 15 Element on the [AuI]-CE/azide 1,3-Dipolar Cycloaddition Reaction". D. González-Pinardo, I. Fernández, Inorg. Chem. 2025, 64, 5628. pdf
398. "Enantioselective photocatalytic synthesis of bicyclo[2.1.1]hexanes as orthodisubstituted benzene bioisosteres with improved biological activity". P. Garrido-García, I. Quirós, P. Milán-Rois, S. Ortega-Gutiérrez, M. Martín-Fontecha, L. A. Campos, Á. Somoza, I. Fernández, T. Rigotti, M. Tortosa, Nat. Chem. 2025, 17, 734. pdf HIGHLIGHTED in Synfacts 2025, 21, 631
397. "Stepwise Alkyne Insertion in Au(I) Acetylides: Influence of the Nuclearity". J. Cayuela-Castillo, F. J. Fernández-de-Córdova, M. S. See, I. Fernández, P. Ríos, Chem. Sci. 2025, 16, 4684. pdf Selected as 2025 Chemical Science HOT Article
396. "An Open-Shell IrII/IrIV Redox Couple Outperforms the Conventional IrI/IrIII Pair for the Catalytic Isomerization of Olefins". A. Pita-Milleiro, N. Hidalgo, J. J. Moreno, I. Fernández, J. Campos, Nat. Chem. 2025, 17, 607. pdf
395. "Extended Tetrathiafulvalene Multi-Redox Systems Incorporating 4,5-Dihydroazuleno[2,1,8-ija]azulene Cores". V. B. R. Pedersen, M. Zalibera, F. Lirette, J. Ouellette, A. Lanza, I. Fernández, P. Rapta, J.-F. Morin, M. B. Nielsen, Angew. Chem. Int. Ed. 2025, 64, e202422275. pdf
394. "Disclosing the intra-catalyst non-covalent interactions in tetrahydropyran-based dipeptidic catalysts". I. García-Monzón, J. Borges-González, E. Q. Morales, I. Fernández, T. Martín, Adv. Synth. Catal. 2025, 367, e202401443. pdf
393. "Insight into the Key Factors that Influence the Reaction Pathways in the Silyl-Prins Cyclization of gem-Vinylsilyl Alcohols". P. González-Andrés, C. Díez-Poza, L. F. Peña, D. Gónzalez-Pinardo, I. Fernández, A. Barbero, Adv. Synth. Catal. 2025, 367, e202401437. pdf
392. "Cross-Dehydrogenative Coupling of Secondary Amines with Silanes Catalyzed by Agostic Iridium-NSi Species". M. Padilla, M. Batuecas, P. García-Orduña, I. Fernández, F. J. Fernández-Álvarez, Inorg. Chem. 2025, 64, 255. pdf
391. "Visible Light-Mediated [4+2] Annulation of Silylimines with Olefins to 1-Aminotetralins Enabled by Diradical Hydrogen Atom Transfer of C−H Bonds". Q. Liu, Y. Huang, X. Zhou, I. Fernández, Y. Xiong, Angew. Chem. Int. Ed. 2025, 64, e202421464. pdf THIS ARTICLE HAS BEEN HIGHLIGHTED (see: Synfacts 2025, 21, 308)
390. "Cooperative hydrogenation catalysis at a constrained gallylene-nickel(0) interface". T. L. Kalkuhl, I. Fernández, T. J. Hadlington, Chem 2025, 11, 102349. pdf
389. "Understanding the Reactivity and Selectivity of Oxazaborolidium ion-Catalyzed Diels-Alder Reactions Involving Cyclobutenones as Dienophiles". S. Portela, I. Fernández, ChemPlusChem 2025, 90, e202400684. pdf invited for the special collection titled From Computer to Bench and Back: In Silico Elucidation of Organocatalytic Reaction Mechanisms
388. "π-Conjugation as a Direct Estimate of Lewis Acidity". D. González-Pinardo, I. Fernández, Chem. Asian J. 2025, 20, e202401212. pdf SELECTED FOR COVER PAGE
387. "Synthesis of Contorted Polycyclic Aromatic Compounds via Alkyne Benzannulation on Dibenzochrysene Derivatives". A. Darvish, F. Lirette, I. Fernández, J.-F. Morin, Chem. Eur. J. 2025, 31, e202403456. pdf