Grupos de investigación

  1. Portada
  2. Publicaciones
  3. Artículos (desde 2015)

Artículos (desde 2015)

  1. T. M. Santos, V. Rigual, J. C. Domínguez, M. V. Alonso, M. Oliet, F. Rodriguez. TFractionation of Pinus radiata by ethanol-based organosolv process. Biomass Conversion and Biorefinery, DOI: 10.1007/s13399-022-02329-z, 2022.
  2. Miguel Ayuso, Pablo Navarro, Cristian Moya, José Palomar, Julián García, Francisco Rodríguez. Extractive Distillation with Ionic Liquids to Separate Benzene, Toluene, and Xylene from Pyrolysis Gasoline: Process Design and Techno-Economic Comparison with the Morphylane Process. Industrial & Engineering Chemistry Research, 61, 2511-2523, 2022
  3. Cynthia Hopson, Victoria Rigual, Juan C. Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. A new approach for the use of cellulose-rich solids from biorefinery in the formulation of gel-like materials. Industrial Crops and Products, 186, 115230, 2021
  4. Cynthia Hopson, Victoria Rigual, Juan C. Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. A new approach for the use of cellulose-rich solids from biorefinery in the formulation of gel-like materials. Industrial Crops and Products, 186, 115230, 2021
  5. Antonio Ovejero-Pérez, Victoria Rigual, Juan Carlos Domínguez, M. Virginia Alonso, Mercedes Oliet, and Francisco Rodriguez. Organosolv and ionosolv processes for autohydrolyzed poplar fractionation: Lignin recovery and characterization. International Journal of Biological Macromolecules, 197, 131-140, 2022.
  6. Cynthia Hopson, M. Mar Villar-Chavero, Juan C. Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. Cellulose ionogels, a perspective of the last decade: A review. Carbohydrate Polymers, 274, 118663, 2021
  7. Miguel Ayuso, Jorge Varela, Noelia García-Somoza, Julián García, Francisco Rodríguez. Experimental screening of ionic liquids as mass agents in the n-hexane/1-hexene extractive distillation. Fluid Phase Equilibria, 549, 113205, 2021
  8. Antonio Ovejero-Pérez, Miguel Ayuso, Victoria Rigual, Juan Carlos Domínguez, Julián García, M. Virginia Alonso, Mercedes Oliet, and Francisco Rodriguez. Technoeconomic Assessment of a Biomass Pretreatment + Ionic Liquid Recovery Process with Aprotic and Choline Derived Ionic Liquids. ACS Sustainable Chem. Eng., 9, 8467−8476, 2021.
  9. Miguel Ayuso, Antonio Ovejero-Pérez, Noemí Delgado-Mellado, Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Tetrathiocyanatocobaltate and bis(trifluoromethylsulfonyl)imide-basedionic liquids as mass agents in the separation of cyclohexane andcyclohexene mixtures by homogeneous extractive distillation. J. Chem. Thermodynamics, 157, 1064032, 2021.
  10. Miguel Ayuso, André M. Palma, Marcos Larriba, Noemí Delgado-Mellado, Julián García, Francisco Rodríguez, João A. P. Coutinho, Pedro J. Carvalho, Pablo Navarro. Experimental and CPA EoS Description of the Key Components in the BTX Separation from Gasolines by Extractive Distillation with Tricyanomethanide-Based Ionic Liquids. Industrial & Engineering Chemistry Research, 59(33), 15058-15068, 2020.
  11. Sandra Rivas, Victoria Rigual, Juan Carlos Domínguez, M. Virginia Alonso, Mercedes Oliet, Juan Carlos Parajó, Francisco Rodriguez. A biorefinery strategy for the manufacture and characterization of oligosaccharides and antioxidants from poplar hemicelluloses. Food and Bioproducts Processing, 123, 398-408, 2020.
  12. Juan C. Dominguez, Belen Del Saz-Orozco, Mercedes Oliet, Maria V. Alonso, Francisco Rodriguez. Thermal degradation kinetics of a lignin particle-reinforced phenolic foam. Journal of Cellular Plastics, nº 0021955X20932889, 2020.
  13. Pablo Navarro, Andre M. Palma, Julian García, Francisco Rodríguez, Joao A.P. Coutinho, Pedro J. Carvalho. High pressure density of tricyanomethanide-based ionic liquids: Experimental and PC-SAFT modelling. Fluid Phase Equilibria, 520, nº 112652, 2020.
  14. Antonio Ovejero-Pérez, Victoria Rigual, Juan Carlos Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. Acidic depolymerization vs ionic liquid solubilization in lignin extraction from eucalyptus wood using the protic ionic liquid 1-methylimidazolium chloride. International Journal of Biological Macromolecules, 157, 461-469, 2020.
  15. Miguel Ayuso, Andrés Canada-Barcala, Marcos Larriba, Pablo Navarro, Noemí Delgado-Mellado, Julián García, Francisco Rodríguez. Enhanced separation of benzene and cyclohexane by homogeneous extractive distillation using ionic liquids as entrainers. Separation and Purification Technology, 240, nº 116583, 2020.
  16. Victoria Rigual, Antonio Ovejero-Pérez, Sandra Rivas, Juan C. Domínguez, M. Virginia Alonso, Mercedes Oliet, and Francisco Rodriguez. Protic, Aprotic, and Choline-Derived Ionic Liquids: Toward Enhancing the Accessibility of Hardwood and Softwood. ACS Sustainable Chemistry & Engineering, 8, 1362-1370, 2020.
  17. M. M. Villar-Chavero, J. C. Domínguez, M. V. Alonso, M. Oliet, F. Rodriguez. Chitosan-reinforced cellulosic bionogels: viscoelastic and antibacterial properties. Carbohydrate Polymers, 115569, 2020.
  18. M. Ayuso, P. Navarro, A. Palma, M. Larriba, N. Delgado-Mellado, J. García, F. Rodríguez, J. A. P. Coutinho, P. J. Carvalho. Toward modeling the aromatic/aliphatic separation by extractive distillation with tricyanomethanide-based ionic liquids using CPA EoS. Industrial & Engineering Chemistry Research, 58, 19681-19692, 2019.
  19. T. M. Santos, V. Rigual, M. Oliet, M. V. Alonso, J. C. Domínguez, F. Rodriguez. Two-step fractionation of Pinus radiata by Autohydrolysis and organosolv delignification for enzymatic hydrolysis. Journal of Chemical Technology and Biotechnology, 94, 3951-3959, 2019.
  20. P. Navarro, A. Ovejero-Pérez, M. Ayuso, N. Delgado-Mellado, M. Larriba, J. García, F. Rodríguez. Cyclohexane/cyclohexene separation by extractive distillation with cyano-based ionic liquids. Journal of Molecular Liquids, 289, 111120, 2019.
  21. N. Delgado-Mellado, M. Ayuso, M. M. Villar-Chavero, J. García, F. Rodríguez. Ecotoxicity evaluation towards Vibrio fischeri of imidazolium- and pyridinium-based ionic liquids for their use in separation processes. SN Applied Sciences, 1(8), 896, 2019.
  22. P. Navarro, I. de Dios-García, M. Larriba, N. Delgado-Mellado, M. Ayuso, D. Moreno, J. Palomar, J. García, F. Rodríguez. Dearomatization of pyrolysis gasoline by extractive distillation with 1-ethyl-3-methylimidazolium tricyanomethanide. Fuel Processing Technology, 195, 106156, 2019.
  23. V. Rigual, J. C. Domínguez, S. Rivas, A. Ovejero-Pérez, M. V. Alonso, M. Oliet, F. Rodriguez. Application of microscopy techniques for a better understanding of biomass pretreatment. Industrial Crops and Products, 138, 111466, 2019.
  24. M. Mar Villar-Chavero, Juan C. Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. Tuning the rheological properties of cellulosic ionogels reinforced with chitosan: The role of the deacetylation degree. Carbohydrate Polymers, 207, 775-781, 2019.
  25. Noemí Delgado-Mellado, Antonio Ovejero-Perez, Pablo Navarro, Marcos Larriba, Miguel Ayuso, Julián García, Francisco Rodríguez. Imidazolium and pyridinium-based ionic liquids for the cyclohexane/cyclohexene separation by liquid-liquid extraction. J. Chem. Thermodynamics, 131, 340-346, 2019.
  26. M. Mar Villar-Chavero, Juan C. Domínguez, Juan C., M. Virginia Alonso, Mercedes Oliet, Rodriguez, Francisco. Thermal and kinetics of the degradation of chitosan with different deacetylation degrees under oxidizing atmosphere. Thermochimica Acta, 670, 18-26, 2018.
  27. Pablo Navarro, Miguel Ayuso, André M. Palma, Marcos Larriba, Noemí Delgado-Mellado, Julian Garcia, Francisco Rodríguez, Joao A. P. Coutinho,  and Pedro J. Carvalho. Toluene/n Heptane Separation by Extractive Distillation with Tricyanomethanide-Based Ionic Liquids: Experimental and CPA EoS Modeling. Industrial & Engineering Chemistry Research, 57(42), 14242-14253, 2018.
  28. Victoria Rigual, Tamara M. Santos, Juan Carlos Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. Evaluation of hardwood and softwood fractionation using autohydrolysis and ionic liquid microwave pretreatment. Biomass and Bioenergy, 117, 190-197.
  29. Noemí Delgado-Mellado, Marcos Larriba, Pablo Navarro, Victoria Rigual, Miguel Ayuso, Julián García, Francisco Rodríguez. Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis. Journal of Molecular Liquids, 260, 37-43, 2018.
  30. Tamara M. Santos, M. Virginia Alonso, Mercedes Oliet, Juan C. Domínguez, Victoria Rigual, Francisco Rodriguez. Effect of autohydrolysis on Pinus radiata wood for hemicellulose extraction. Carbohydrate Polymers, 194, 285-293, 2018.
  31. Pablo Navarro, Marcos Larriba, Noemí Delgado-Mellado, Miguel Ayuso, Marta Romero, Julián García, Francisco Rodríguez. Experimental screening towards developing ionic liquid-based extractive distillation in the dearomatization of refinery streams. Separation and Purification Technology, 201, 268-275, 2018.
  32. Marcos Larriba, Noemí Delgado-Mellado, Pablo Navarro, Roberto Alcover, Cristian Moya, JoséPalomar, Julian Garcia, and Francisco Rodríguez. Novel Process to Reduce Benzene, Thiophene, and Pyrrole in Gasoline Based on [4bmpy][TCM] Ionic Liquid. Energy & Fuels, 32, 5650-5658, 2018.
  33. Victoria Rigual, Tamara M. Santos, Juan Carlos Domínguez, M. Virginia Alonso, Mercedes Oliet, Francisco Rodriguez. Combining autohydrolysis and ionic liquid microwave treatment to enhance enzymatic hydrolysis of Eucalyptus globulus wood. Bioresource Technology, 251, 197-203, 2018.
  34. Emilio J. Gonzalez, José Palomar, Pablo Navarro, Marcos Larriba, Julian Garcia, Francisco Rodriguez. On the volatility of aromatic hydrocarbons in ionic liquids: Vapor-liquid equilibrium measurements and theoretical analysis. Journal of Molecular Liquids, 250, 9-18, 2018.
  35. Marcos Larriba, Miguel Ayuso, Pablo Navarro, Noemí Delgado-Mellado, Maria Gonzalez-Miquel, Julian García, and Francisco Rodríguez. Choline Chloride-Based Deep Eutectic Solvents in the Dearomatization of Gasolines. ACS Sustainable Chemistry & Engineering, 6(1), 1031-1047, 2018
  36. Marcos Larriba, Juan de Riva, Pablo Navarro, Daniel Moreno, Noemí Delgado-Mellado, Julián García, Victor R. Ferro, Francisco Rodríguez, José Palomar. COSMO-based/Aspen Plus process simulation of the aromatic extraction from pyrolysis gasoline using the {[4empy][NTf2] + [emim][DCA]} ionic liquid mixture. Separation and Purification Technology, 190, 211-227, 2018.
  37. Juan C. Domínguez, Tamara M. Santos, Victoria Rigual, Mercedes Oliet, Maria V. Alonso, Francisco Rodriguez. Thermal stability, degradation kinetics, and molecular weight of organosolv lignins from Pinus radiata. Industrial Crops & Products, 111, 889-898, 2018.
  38. Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Design of the hydrocarbon recovery section from the extract stream of the aromatic separation from reformer and pyrolysis gasolines using a binary mixture of [4empy][Tf2N] + [emim][DCA] Ionic Liquids. Energy & Fuels. 31(1), 1035-1043, 2017.
  39. Moya, Cristian; Gonzalez-Miquel, Maria; Rodriguez, Francisco; Soto, Ana; Rodriguez, Hector; Palomar, Jose.  Non-ideal behavior of ionic liquid mixtures to enhance CO2 capture. Fluid Phase Equilibria, 450, 175-183, 2017.
  40. Victoria Rigual, Tamara M. Santos, Juan C. Dominguez, Maria V. Alonso, Mercedes Oliet, Francisco Rodriguez. Recovery and Reuse of 1-AllyI-3-methylimidazolium Chloride in the Fractionation of Pinus radiata Wood. ACS Sustainable Chemistry & Engineering, 5(3), 2384-2392, 2017.
  41. Navarro, Pablo; Larriba, Marcos; Delgado-Mellado, Noemi; Sanchez-Migallon, Pablo; Garcia, Julian; Rodriguez, Francisco. Extraction and recovery process to selectively separate aromatics from naphtha feed to ethylene crackers using 1-ethyl-3-methylimidazolium thiocyanate ionic liquid. Chemical Engineering Research & Design, 120, 102-112, 2017.
  42. Larriba, Marcos; Navarro, Pablo; Delgado-Mellado, Noemi; Stanisci, Victor; Garcia, Julian; Rodriguez, Francisco. Extraction of aromatic hydrocarbons from pyrolysis gasoline using tetrathiocyanatocobaltate-based ionic liquids: Experimental study and simulation. Fuel Processing Technology, 159, 96-110, 2017.
  43. Navarro, Pablo; Crespo, Emanuel A.; Costa, Joao M. L.; Llovell, Felix; Garcia, Julian; Rodriguez, Francisco; Carvalho, Pedro J.; Vega, Lourdes F.; Coutinho, Joao A. P. New Experimental Data and Modeling of Glymes: Toward the Development of a Predictive Model for Polyethers. Industrial & Engineering Chemistry Research, 56(27), 7830-7844, 2017.
  44. Larriba, Marcos; Navarro, Pablo; Delgado-Mellado, Noemi; Gonzalez, Carlos; Garcia, Julian; Rodriguez, Francisco. Dearomatization of Pyrolysis Gasoline with an Ionic Liquid Mixture: Experimental Study and Process Simulation. AICHE Journal, 63(9), 4054-4065, 2017.
  45. 22.    Juan Carlos Domínguez, Belén del Saz-Orozco, Mercedes Oliet, M. Virginia Alonso, Francisco Rodríguez. Thermal properties and thermal degradation kinetics of phenolic and Wood flour-reinforced phenolic foams. J. Compos. Mater. 51(1), 125-138, 2017.
  46. Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Design of the hydrocarbon recovery section from the extract stream of the aromatic separation from reformer and pyrolysis gasolines using a binary mixture of [4empy][Tf2N] + [emim][DCA] Ionic Liquids. Energy & Fuels. 31(1), 1035-1043, 2017.
  47. Marcos Larriba, Pablo Navarro, Noemí Delgado-Mellado, Victor Stanisci, Julián García, Francisco Rodríguez. Separation of aromatics from n-alkanes using tricyanomethanide-based ionic liquids: liquid-liquid extraction, vapor-liquid separation, and thermophysical characterization. J. Mol. Liq. 223, 880–889, 2016.
  48. Emilio J. González, Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. A comparative study of pure ionic liquids and their mixtures as potential mass agents in the separation of hydrocarbons. J. Mol. Liq. 222, 118 – 124, 2016.
  49. Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Vapor-Liquid Equilibria for (n-Hexane, n-Octane, Cyclohexane, or 2,3-Dimethylpentane) + Toluene + {[4empy][Tf2N] (0.3) + [emim][DCA] (0.7)} Mixed Ionic Liquids. J. Chem. Eng. Data 61, 2440 – 2449, 2016.
  50. Marcos Larriba, Pablo Navarro, María González-Miquel, Salama Omar, José Palomar, Julián García, Francisco Rodríguez. Dicyanamide-based ionic liquids in the liquid-liquid extraction of aromatics from alkanes: Experimental evaluation and computational predictions. Chem. Eng. Res. Des. 109, 561 – 572, 2016.
  51. Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Vapor-liquid equilibria for n-heptane + (benzene, toluene, p-xylene, or ethylbenzene) + {[4empy][Tf2N] (0.3) + [emim][DCA] (0.7)} binary ionic liquid mixture. Fluid Phase Equilib. 417, 41 – 49, 2016.
  52. Pablo Navarro, Marcos Larriba, Julián García, Emilio J. González, Francisco Rodríguez. Selective recovery of aliphatics from aromatics in the presence of the {[4empy][Tf2N] + [emim][DCA]} ionic liquid mixture. J. Chem. Thermodyn. 96, 134 – 142, 2016.
  53. Marcos Larriba, Salama Omar, Pablo Navarro, Julián Garcia, Francisco Rodriguez, María Gonzalez-Miquel. Recovery of tyrosol from aqueous streams using hydrophobic ionic liquids: a first step towards developing sustainable processes for olive mill wastewater (OMW) management. RSC Advances, 6(23), 18751-18762, 2016.
  54. Pablo Navarro, Marcos Larriba, Julián García, Emilio J. González, Francisco Rodríguez. Vapor-Liquid Equilibria of n-Heptane + Toluene + 1-Ethyl-4-methylpyridinium Bis(trifluoromethylsulfonyl)imide Ionic Liquid. J. Chem. Eng. Data 61, 458 – 465, 2016.
  55. Emilio J. González, Pablo Navarro, Marcos Larriba, Julián García, Francisco Rodríguez. Use of selective ionic liquids and ionic liquid/salt mixtures as entrainer in a (vapor + liquid) system to separate n-heptane from toluene. J. Chem. Thermodyn. 91, 156 – 164, 2015.
  56. Marcos Larriba, Pablo Navarro, Emilio J. González, Julián García, Francisco Rodríguez. Dearomatization of pyrolysis gasolines from mild and severe cracking by liquid–liquid extraction using a binary mixtures of [4empy][Tf2N] and [emim][DCA] ionic liquids. Fuel Processing Technol. 137, 269 – 282, 2016.
  57. Marcos Larriba, Pablo Navarro, Emilio J. González, Julián García, Francisco Rodríguez. Separation of BTEX from a naphtha feed to ethylene crackers using a binary mixtures of [4empy][Tf2N] and [emim][DCA] ionic liquids. Sep. Purif. Technol. 144, 54 – 62, 2015.
  58. Pablo Navarro, Marcos Larriba, Julián García, Emilio J. González, Francisco Rodríguez.Vapor-liquid equilibria of {n-heptane + toluene + [emim][DCA]} system by headspace gas chromatography. Fluid Phase Equilib. 387, 209 – 216, 2015.
  59. Pablo Navarro, Marcos Larriba, Jean-Baptiste Beigbeder, Julián García, Francisco Rodríguez. Thermal stability and specific heats of {[bpy][BF4] + [bpy][Tf2N]} and {[bpy][BF4] + [4bmpy][Tf2N]} mixed ionic liquid solvents. J. Therm. Anal. Calorim. 119, 1235 – 1243, 2015.
  60. Marcos Larriba, Pablo Navarro, Jean-Baptiste Beigbeder, Julián García, Francisco Rodríguez. Mixing and decomposition behavior of {[4bmpy][Tf2N] + [emim][EtSO4]} and {[4bmpy][Tf2N] + [emim][TFES]} ionic liquid mixtures. J. Chem. Thermodyn. 82, 58 – 75, 2015.
  61. Belen Del Saz-Orozco, María Virginia Alonso, Mercedes Oliet, Juan Carlos Domínguez, Ester Rojo, Francisco Rodriguez. Lignin particle- and wood flour-reinforced phenolic foams: Friability, thermal stability and effect of hygrothermal aging on mechanical properties and morphology. Composites Part B: Engineering. 80, 154-161, 2015.
  62. Belen Del Saz-Orozco, María Virginia Alonso, Mercedes Oliet, Juan Carlos Domínguez, Francisco Rodriguez. Mechanical, thermal and morphological characterization of cellulose fiber-reinforced phenolic foams. Composites Part B: Engineering. 75, 367-372, 2015.
  63. Ester Rojo, María V. Alonso, Belén Del Saz-Orozco, Mercedes Oliet, Francisco Rodriguez. Optimization of the silane treatment of cellulosic fibers from eucalyptus wood using response surface methodology. Journal of Applied Polymer Science. 112(26), 42157-42166, 2015.
  64. Ester Rojo, María V. Alonso, Mercedes Oliet, Belén Del Saz-Orozco, Francisco Rodriguez. Effect of fiber loading on the properties of treated cellulose fiber-reinforced phenolic composites. Composites Part B: Engineering. 68, 185-192, 2015.